| Reviews | Bonding and Stereochemistry | Van der Waals Interactions | Metallophilic Interactions | Delocalized Bonding | Stereo-spin Isomerism | Metal-metal Bonding
S. Alvarez, E. Ruiz. "Self-Assembly of Coordination Compounds: Design Principles", in Supramolecular Chemistry, From Molecules to Nanomaterials, J. W. Steed, P. A. Gale, eds., John Wiley & Sons, Chichester, UK, 2012, 5, 1993-2044. ISBN 978-0-470-74640-0 |
E. Ruiz, J. Cirera and S. Alvarez, "Spin density distribution in transition metal complexes", Coord. Chem. Rev. 2005, 249, 2649-2660. |
S. Alvarez, "Bonding and stereochemistry of three-coordinated transition metal compounds", Coord. Chem. Rev. 1999, 193-5, 13-41. |
S. Alvarez. "Coordinating Ability of Anions, Solvents and Gases Towards Ions of Alkaline and alkaline-Earth Metals, Transition Metals, and Lanthanides. Chem. Eur. J., 2020, 26, 4350-4377. doi: 10.1002/chem.201905453. |
J. D. Velasquez, J. Echeverría, S. Alvarez. “Delocalized Bonding in Li2X2 Frameowrks. Probing the Limits of the Covalent and Ionic Bonding Models”. Inorg. Chem., 2021, 60, 345-356. |
P. Alemany, A. D'Aléo, M. Giorgi, E. Canadell and F. Fages. "C-H···BF2O2 interactions in crystals: a case for boron hydrogen bonding?".Cryst. Growth Des., 2014, 14, 3700-3703. |
J. Echeverría, G. Aullón and S. Alvarez. "Dihydrogen Interactions in Group 13 Compounds". Dalton Trans., 2017, 46, 2844-2854. Doi: 10.1039/c6dt02854c. Open access. |
M. Ferrer, D. Gómez-Bautista, A. Gutiérrez, G. Orduña-Marco, L. A. Oro, J. J. Pérez-Torrente, O. Rossell and E. Ruiz. "Pyridinethiolate Titanocene Metalloligands and their Self-Assembly Reactions to Yield Early-Late Metallamacrocycles." Organometallics, 2016, 35, 336-345. |
R. Hoffmann, S. Alvarez, C. Mealli, A. Falceto, T. J. Cahill, T. Zeng and G. Manca. "From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields". Chem. Rev., 2016, 116, 8173-8192. Doi: 10.1021/acs.chemrev.6b00251. |
A. Falceto, K. H. Theopold and S. Alvarez, "Cr-Cr Quintuple Bonding: Ligand Topology and Interplay Between Metal-Metal and Metal-Ligand Bonding". Inorg. Chem., 2015, 54, 10966-10977. Doi: 10.1021/acs.inorgchem.5b02059, open access.
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S. Alvarez, "What do we mean when we talk about bonds". Chem. World, 2015, 12, 36-37. |
J. Adhikary, P. Kundu, S. Dasgupta, S. Mukherjee, S. Chattopadhyay, G. Aullón, D. Das, "Nickel(II) Complexes having Different Configurations controlled by N,N,O-donor Schiff-base Ligands in Presence of Isothiocyanate as Co-ligand: Synthesis, Structures, Comparative Biological Activity and DFT Study". Polyhedron 2015, 101, 93-102, Doi: 10.1016/j.poly.2015.07.055 |
J. Fernández-Valparís and S. Alvarez. "Design of a Structural Database for Homoleptic Transition Metal Complexes". Struct. Chem., 2015, 26, 1715-1723. Doi:10.1007/s11224-015-0651-3. |
A. Falceto, E. Carmona and S. Alvarez. "Electronic and Structural Effects of Low Hapticity Coordination of Arene Rings to Transition Metals". Organometallics 2014, 33, 6660-6668. Doi: 10.1021/om5009583. |
A. Falceto, D. Casanova and S. Alvarez. "Distortions of π-coordinated Arenes with Anionic Character". Chem. Eur. J., 2014, 20, 14674-14689.Doi: 10.1002/chem.201403889. |
G. Aullón and B. Peigné. "Structural Analysis of the Coordination of Dinitrogen to Transition Metal Complexes”. Acta Cryst., Sect B, 2015, 71, 369-386. Doi: 10.1107/S2052520615006083. |
A. Mondragón, M. Flores-Alamo, P. R. Martínez-Alanis, G. Aullón, V. M. Ugalde-Saldívar and I. Castillo. "Electrocatalytic Proton Reduction by Dimeric Nickel Complex of a Sterically Demanding Pincer-type NS2 Aminobis(thiophenolate) Ligand”. Inorg. Chem., 2015, 54, 619−627. |
M. Carrasco, I. Mendoza, E. Alvarez, C. Maya, R. Peloso, A. Rodríguez, A. Falceto, S. Alvarez and E. Carmona. "Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands". Chem. Eur. J., 2015, 21, 410-421. Doi: 10.1002/chem.201404057 |
L. J. K. Cook, R. Mohammed, G. Sherborne, S. Alvarez and M. Halcrow, “Spin-state Behaviour of Iron(II)Dipyrazolylpyridine Complexes. New Insights from Crystallographic and Solution Measurements". Coord. Chem. Rev., 2015, 289-290, 2-12. Doi: 10.1016/j.ccr.2014.08.006. |
C. Fliedel, V. Rosa, C. I. M. Santos, P. J. Gonzalez, R. M. Almeida, C. S. B. Gomes, P. T. Gomes, M. A. N. D. A. Lemos, G. Aullón, R. Welter and T. Avilés, “Synthesis, Structural Characterisation, and Density Functional Theory Studies of Ar-BIAN Cu(II) Complexes: Application in the Reverse Atom-Transfer Radical Polymerisation of Styrene” Dalton Trans., 2014, 43, 13041-13054. |
A. G. Algarra, G. Aullón,P. V. Bernhardt, M. Martínez, “Computational Insights on the Chemistry of Cu(II) with a Mixed-donor N3S3 Macrobicyclic Ligand” Inorg. Chem., 2014, 53, 512-521. |
S. Alvarez, B. Menjón. "Modulation of the Coordination Sphere of f-Element Complexes by Fluorocarbons", highlight, Angew. Chem. Int. Ed., 2014, 53, 2810-2811. Doi 10.1002/anie.201310916. |
C. Dryzun, P. Alemany, D. Casanova, D. Avnir. "A Continuous Symmetry Analysis of Chemical Bonding". Chem. Eur. J. 2011, 17, 6129-6141 |
R. Diaz-Torres and S. Alvarez, "Coordinating ability of anions and solvents towards transition metals and lanthanides", Dalton Trans. 2011, 40, 10742-10750. |
J. C. Knight, S. Alvarez, A. J. Amoroso, P. G. Edwards and N. Singh, "A novel bipyridine-based hexadentate tripodal framework with a strong preference for trigonal prismatic co-ordination geometries", Dalton Trans. 2010, 39, 3870-3883. |
E. Cremades, J. Echeverría, S. Alvarez. "The Trigonal Prism in Coordination Chemistry". Chem. Eur. J. 2010, 16, 10389-10396 |
A. Ruiz-Martínez, D. Casanova, S. Alvarez. "Ligand Association/Dissociation Paths and Ill Defined Coordination Numbers". Chem. Eur. J. 2010, 16, 6567-6581 |
G. Aullon and S. Alvarez, "Oxidation states, atomic charges and orbital populations in transition metal complexes", Theor. Chem. Acc. 2009, 123, 67-73. |
A. Ruiz-Martínez, S. Alvarez. “Stereochemistry of Compounds with Coordination Number Ten”. Chem. Eur. J. 2009, 15, 7470-7480 |
J. Echeverría, E. Cremades, A. J. Amoroso, S. Alvarez. "Jahn-Teller Distortions of Six-coordinate Copper(II) Compounds: Cis or Trans?". Chem. Commun. 2009, 4242-4244 |
D. Aguila, E. Escribano, S. Speed, D. Talancon, L. Yerman and S. Alvarez, "Calibrating the coordination chemistry tool chest: metrics of bi- and tridentate ligands", Dalton Trans. 2009, 6610-6625. |
A. Ruiz-Martínez, D. Casanova, S. Alvarez. "Polyhedral Structures with an Odd Number of Vertices: Nine-Coordinate Metal Compounds". Chem. Eur. J. 2008, 14, 1291-1303 |
A. Ruiz-Martínez, D. Casanova, S. Alvarez. "Polyhedral Structures with an Odd Number of Vertices: Nine-atom Clusters and Supramolecular Architectures". Dalton Trans., 2008, 2583-2591 |
B. Cordero, V. Gomez, A. E. Platero-Prats, M. Reves, J. Echeverria, E. Cremades, F. Barragan and S. Alvarez, "Covalent radii revisited", Dalton Trans. 2008, 2832-2838. |
G. Aullon and S. Alvarez, "On the existence of molecular palladium(VI) compounds: Palladium hexafluoride", Inorg. Chem. 2007, 46, 2700-2703. |
S. Alvarez. "Nesting of Fullerenes and Frank-Kasper Polyhedra". Dalton Trans., 2006, 2045-2051. |
D. Casanova, M. Llunell, P. Alemany, S. Alvarez. "The Rich Stereochemistry of Eight-Vertex Polyhedra in Chemistry. A Continuous Shape Measures Study". Chem. Eur. J. 2005, 11, 1479-1494 |
S. Alvarez. "Polyhedra in (Inorganic) Chemistry". Dalton Trans. 2005, 2209-2233. |
G. Aullon and S. Alvarez, "Formation of sulfur-sulfur bonds in copper complexes", Eur. J. Inorg. Chem. 2004, 4430-4438. |
E. C. Brown, N. W. Aboelella, A. M. Reynolds, G. Aullon, S. Alvarez and W. B. Tolman, "A new class of (μ-η2:η2-disulfido)dicopper complexes: Synthesis characterization and disulfido exchange", Inorg. Chem. 2004, 43, 3335-3337. |
J. Cirera, P. Alemany, S. Alvarez. "Mapping the Stereochemistry and Symmetry of Tetracoordinate Transition Metal Complexes". Chem. Eur. J. 2004, 10, 190-207. |
D. Casanova, P. Alemany, J. M. Bofill, S. Alvarez. "Shape and Symmetry of Heptacoordinated Transition Metals: Structural Trends". Chem. Eur. J., 2003, 9, 1281-1295 |
G. Aullon and S. Alvarez, "Molecular structure and isomerization in square-planar edge-sharing dinuclear complexes with alkynyl bridges", Organometallics 2002, 21, 2627-2634. |
G. Aullon, E. Ruiz and S. Alvarez, "Theoretical clues to the mechanism of dioxygen formation at the oxygen-evolving complex of photosystem II", Chem. Eur. J. 2002, 8, 2508-2515. |
A. Carvajal, X. Y. Liu, P. Alemany, J. J. Novoa and S. Alvarez, "Ligand effects and dimer formation in dicoordinated copper(I) complexes", Int. J. Quantum Chem. 2002, 86, 100-105. |
G. Aullon, A. Lledos and S. Alvarez, "Hexakis(silyl)palladium(VI) or palladium(II) with η2-disilane ligands?" Angew. Chem. Int. Ed. 2002, 41, 1956. |
A. A. Palacios, P. Alemany and S. Alvarez, "Structure and bonding in late transition metal dinuclear complexes with local trigonal planar geometries", J. Chem. Soc.. Dalton Trans. 2002, 2235-2243. |
G. Aullon and S. Alvarez, "The [M2(CO)8] complexes of the cobalt group", Eur. J. Inorg. Chem. 2001, 3031-3038. |
G. Aullon and S. Alvarez, "Molecular structures of edge-sharing square-planar dinuclear complexes with unsaturated bridges", Inorg. Chemi. 2001, 40, 4937-4946. |
G. Aullon and S. Alvarez, "Theoretical study of bonding, structure, and vibrational spectra of the [Fe2(CO)8]2- anion and its derivatives", Organometallics 2001, 20, 818-826. |
G. Aullon, G. Ujaque, A. Lledos and S. Alvarez, "Edge-sharing binuclear d8 complexes with XR bridges: Theoretical and structural database study of their molecular conformation", Chem. Eur. J. 1999, 5, 1391-1410. |
P. Alemany, J. Llanos and S. Alvarez, "Tetrahedral d0 and d10 transition metal ions sharing edges in the solid state: electronic structure and bonding", J. Chem. Soc. Dalton Trans. 1999, 1235-1240. |
A. A. Palacios, P. Alemany and S. Alvarez, "Electronic structure and bonding in tricoordinate amido complexes of transition metals", Inorg. Chem. 1999, 38, 707-715. |
G. Aullon, G. Ujaque, A. Lledos, S. Alvarez and P. Alemany, "To bend or not to bend: Dilemma of the edge-sharing binuclear square planar complexes of d8 transition metal ions", Inorg. Chem. 1998, 37, 804-813. |
J. V. Cuevas, A. A. Palacios and S. Alvarez, "Electronic structure and bonding in the Hoppe anions [Fe2O5]6- and [Co2O4]4-", New J. Chem. 1997, 21, 301-308. |
G. Aullon and S. Alvarez, "Axial bonding capabilities of square planar d8-ML4 complexes. Theoretical study and structural correlations", Inorg. Chem. 1996, 35, 3137-3144. |
V. Zhukov, F. Boucher, P. Alemany, M. Evain and S. Alvarez, "Electronic-Structure, Chemical Bonding, and Jahn-Teller Distortions in CdPS3", Inorg. Chem. 1995, 34, 1159-1163. |
P. Alemany and R. Hoffmann, "Toroidal Nickel Thiolates - Structure and Bonding", J. Am. Chem. Soc. 1993, 115, 8290-8297. |
G. A. Carriedo, N. G. Connelly, S. Alvarez, E. Perezcarreno and S. Garciagranda, "Mixed Valency in Binuclear Cyano-Bridged Manganese Bis(Carbonyl) Complexes and Stereochemical Control of Their Oxidation - a Molecular-Orbital Study", Inorg. Chem. 1993, 32, 272-276. |
F. Arnau, F. Mota, J. J. Novoa and S. Alvarez, "On the Existence of a Quadruplet Ground-State for the BO2 and AiO2 Molecules", Quantum Chemistry: Basic Aspects, Actual Trends 1989, 62, 377-383. |
A. Labarta, E. Molins, X. Vinas, J. Tejada, A. Caubet and S. Alvarez, "Electronic-Structure Determination of Iron(Ii) Phthalocyanine Via Magnetic-Susceptibility and Mössbauer Measurements", J. Chem. Phys. 1984, 80, 444-448. |
S. Alvarez and C. Lopez, "Linkage Isomerism in Cyanoaquobis(Dimethyl-Glyoximato)Cobalt(III)", Inorg. Chim. Acta Lett. 1982, 64, L99-L100. |
J. Echeverría. "Abundance and Strength of M–H···H–C (M = Al, Ga, In) Dihydrogen Bonds". Cryst. Growth Des. 2017, in press. Doi: 10.1021/acs.cgd.7b00069. |
J. Echeverría, G. Aullón and S. Alvarez. "Dihydrogen Interactions in Group 13 Compounds". Dalton Trans., 2017, 46, 2844-2854. Doi: 10.1039/c6dt02854c. Open access. |
S. Shaik and S. Alvarez. Reply to "Entropic factors also contribute to the high melting points of polyhedral alkanes". Nature Chem., 2015, 7, 87-90. |
J. Vogt, S. Alvarez. "On the Van der Waals Radii of the Noble Gases". Inorg. Chem., 2014, 53, 9260-9266. Doi 10.1021/ic501364h; corrections: Doi 10.1021/ic502140y. |
S. Alvarez. "A Cartography of the Van der Waals Territory". Dalton Trans., 2013, 42, 8617. |
D. Danovich, S. Shaik, F. Neese, J. Echeverría, G. Aullón, S. Alvarez. "Understanding the Nature of the CH···HC Interaction in Alkanes", J. Chem. Theor. Comput., 2013, 9, 1977. |
J. Echeverria, G. Aullon, D. Danovich, S. Shaik and S. Alvarez, "Dihydrogen contacts in alkanes are subtle but not faint", Nature Chem. 2011, 3, 323-330. |
A. Ibarz, E. Ruiz and S. Alvarez, "Theoretical study of the guest···guest interactions of cobaltocene intercalated in metal sulfides", J. Chem. Soc. Dalton Trans. 2000, 1463-1467. |
G. Aullon, D. Bellamy, L. Brammer, E. A. Bruton and A. G. Orpen, "Metal-bound chlorine often accepts hydrogen bonds", Chem. Commun. 1998, 653-654. |
E. Ruiz and S. Alvarez, "Theoretical-Study of Host····Guest Interactions in Clathrates with a Cd(CN)2 Host", Inorg. Chem. 1995, 34, 5845-5851. |
E. Ruiz and S. Alvarez, "Host-Guest Interactions in the Pyrrole and Aniline Hofmann Clathrates - a Theoretical-Study", Inorg. Chem. 1995, 34, 3260-3269. |
E. Ruiz and S. Alvarez, "Intercalation of Halogen Molecules in Alkali Fluoride Lattices - a Theoretical-Study", J. Am. Chem. Soc. 1995, 117, 2877-2883. |
E. Ruiz, J. J. Novoa and S. Alvarez, "Ab-Initio Study of the Intermolecular Interactions in the Hofmann Clathrates", J. Phys. Chem. 1995, 99, 2296-2306. |
E. Ruiz, S. Alvarez, R. Hoffmann and J. Bernstein, "Crystal Orbital Displacement Analysis of Interactions in the Solid-State - Application to the Study of Host-Guest Interactions in the Hofmann Clathrates", J. Am. Chem. Soc. 1994, 116, 8207-8221. |
M.-R. Azani, O. Castillo, M. L. Gallego, T. Parella, G. Aullón, O. Crespo, A. Laguna, S Alvarez, R. Mas-Ballesté, F. Zamora. "The structural Diversity Triggered by Intermolecular Interactions between AuIS2 groups: Aurophilia and Beyond". Chem. Eur. J., 2012, 18, 9965-9976. |
M. A. Carvajal, S. Alvarez and J. J. Novoa, "The nature of the AuI···AuI interactions between cationic [AuL2]+ complexes in the solid state", Theor. Chem. Acc. 2006, 116, 472-479. |
S. Alvarez, G. Aullon, R. Fandos, J. L. G. Fierro, P. Ocon, A. Otero, S. Rojas and P. Terreros, "A pyrimidine thiolate Rh(I) complex: structure, bonding and one-dimensional interactions in solid and in solution", Dalton Trans. 2005, 938-944. |
M. A. Carvajal, S. Alvarez and J. J. Novoa, "The nature of intermolecular CuI···CuI interactions: A combined theoretical and structural database analysis", Chem. Eur. J. 2004, 10, 2117-2132. |
A. Buljan, M. Llunell, E. Ruiz and P. Alemany, "Color and conductivity in Cu2O and CuAlO2: A theoretical analysis of d10···d10 interactions in solid-state compounds", Chem. Mater. 2001, 13, 338-344. |
G. Aullon and S. Alvarez, "Chain conformation and metal···metal contacts in dimers and stacks of d8-ML4 complexes: Electronic effects", Chem. Eur. J. 1997, 3, 655-664. |
G. Aullon, P. Alemany and S. Alvarez, "On the existence of a pyramidality effect in d8···d8 contacts. Theoretical study and structural correlation", Inorg. Chem. 1996, 35, 5061-5067. |
J. J. Novoa, G. Aullon, P. Alemany and S. Alvarez, "On the Bonding Nature of the M···M Interactions in Dimers of Square-Planar Pt(Ii) and Rh(I) Complexes", J. Am. Chem. Soc. 1995, 117, 7169-7171. |
S. Alvarez, P. Alemany, G. Aullon, A. A. Palacios and J. J. Novoa, "Heterodox bonding effects between transition metal atoms", Synergy between Dynamics and Reactivity at Clusters and Surfaces 1995, 465, 241-255. |
M. Corbella, S. Alvarez and J. Ribas, "Synthesis, Characterization and Study of the Pt-Pt Interaction in Cis-[(Aa)(Bb)FCr-NC-Pt(CN)3] (Aa, Bb = Bidentate Amine)", Inorg. Chim. Acta 1986, 121, 13-17. |
Y. Jiang, S. Alvarez and R. Hoffmann, "Binuclear and Polymeric Gold(I) Complexes", Inorg. Chem. 1985, 24, 749-757. |
R. Carrasco, G. Aullon and S. Alvarez, "X-X Through-Cage Bonding in Cu, Ni, and Cr Complexes with M3X2 Cores (X = S, As)", Chem. Eur. J. 2009, 15, 536-546. |
S. Alvarez, R. Hoffmann and C. Mealli, "A Bonding Quandary -or- A Demonstration of the Fact That Scientists Are Not Born With Logic", Chem. Eur. J. 2009, 15, 8358-8373. |
J. Poater, J. M. Bofill, P. Alemany and M. Sola, "Local aromaticity of the lowest-lying singlet states of [n]acenes (n=6-9)", J. Phys. Chem. A 2005, 109, 10629-10632. |
G. Portella, J. Poater, J. M. Bofill, P. Alemany and M. Sola, "Local Aromaticity of [n]acenes, [n]phenacenes, and [n]helicenes (n=1-9)", J. Org. Chem. 2005, 70, 2509-2521. |
G. Aullon, M. Hamidi, A. Lledos and S. Alvarez, "Chalcogen-chalcogen bonds in edge-sharing square-planar d8 complexes. Are they possible?" Inorg. Chem. 2004, 43, 3702-3714. |
R. S. Simons, K. J. Galat, J. D. Bradshaw, W. J. Youngs, C. A. Tessier, G. Aullon and S. Alvarez, "Reaction chemistry, NMR spectroscopy, and X-ray crystallography of [Fe2(μ-SiMe2)2(CO)4] and [Fe2(μ-SiMeCl)2(CO)4]. Electronic structure and bonding in Fe2E2 rings of [Fe2(μ-ER2)2(CO)4] binuclear complexes (E = C, Si, Ge, Sn, Pb)", J. Organomet. Chem. 2001, 628, 241-254. |
X. Y. Liu, A. A. Palacios, J. J. Novoa and S. Alvarez, "Framework bonding and coordination sphere rearrangement in the M2X2 cores of synthetic analogues of oxyhemocyanin and related Cu and Pt complexes", Inorg. Chem. 1998, 37, 1202-1212. |
G. Aullon, P. Alemany and S. Alvarez, "Through-Ring Bonding in Edge-Sharing Dimers of Square-Planar Complexes", J. Organomet. Chem. 1994, 478, 75-82. |
P. Alemany and S. Alvarez, "Bonding and Structure in L4M2(μ-XRn)2 Diamonds of Tetrahedral d10 Ions - Effect of Substituents on the M···M Interaction", Inorg. Chem. 1992, 31, 4266-4275. |
C. Lopez, S. Alvarez, X. Solans and M. Fontaltaba, "Structural, NMR and Theoretical-Study of Delocalization in Cobaloximes", Inorg. Chim. Acta 1986, 111, L19-L21. |
C. Fliedel, V. Rosa, A. Falceto, P. Rosa, S. Alvarez and P. Braunstein, "Substituent Effects in N-(thioether)-Functionalized Bis(Diphenylphosphino)amine-type Ligands on the Coordination Sphere of Iron(II) Complexes: Structures, Magnetism and Bonding". Inorg. Chem., 2015, 54, 6547-6559. Doi: 10.1021/acs.inorgchem.5b00834. |
S. Canton, X. Zhang, L. Lawson Daku, Y. Liu, J. Zhang and S. Alvarez. "Mapping the Ultrafast Changes of Continuous Shape Measures in Photoexcited Spin Crossover Complexes without Long-Range Order". J. Phys. Chem. C. 2015, 119, 3322-3330. Doi:10.1021/jp5117189. |
L. J. K. Cook, R. Mohammed, G. Sherborne, S. Alvarez and M. Halcrow, “Spin-state Behaviour of Iron(II)Dipyrazolylpyridine Complexes. New Insights from Crystallographic and Solution Measurements". Coord. Chem. Rev., 2015, 289-290, 2-12. Doi: 10.1016/j.ccr.2014.08.006. |
J. Cirera, S. Alvarez. “Stereo-spin Isomerism in Pentacoordinate Iron Porphyrin Complexes: The case of [Fe(porphyrinato(CN)]- Systems”, Dalton Trans. 2013, 42, 7002. |
V. Gomez, M. Corbella and G. Aullon, "Two Temperature-Independent Spinomers of the Dinuclear MnIII Compound [{Mn(H2O)(phen)}2(µ2-ClC6H4COO)2(µ-O)](ClO4)2", Inorg. Chem. 2010, 49, 1471-1480. |
J. Cirera, E. Ruiz and S. Alvarez, "Stereochemistry and spin state in four-coordinate transition metal compounds", Inorg. Chem. 2008, 47, 2871-2889. |
D. Maganas, P. Kyritsis, G. Aullon and S. Alvarez, "Ligands that enforce unnatural stereospinomers", Dalton Trans. 2008, 2235-2237. |
F. Pointillart, C. Train, F. Villain, C. C. D. Moulin, P. Gredin, L. M. Chamoreau, M. Gruselle, G. Aullon, S. Alvarez and M. Verdaguer, "Six-fold oxygen-coordinated triplet (S=1) palladium(II) moieties templated by tris(bipyridine)ruthenium(II) ions", J. Am. Chem. Soc. 2007, 129, 1327-1334. |
J. Cirera, E. Ruiz and S. Alvarez, "Shape and spin state in four-coordinate transition-metal complexes: The case of the d6 configuration", Chem. Eur. J. 2006, 12, 3162-3167. |
S. Alvarez and J. Cirera, "How high the spin? Allowed and forbidden spin states in transition-metal chemistry", Angew. Chem. Int. Ed. 2006, 45, 3012-3020. |
E. Ruiz, J. Cirera and S. Alvarez, "Spin density distribution in transition metal complexes", Coord. Chem. Rev. 2005, 249, 2649-2660. |
J. Cano, E. Ruiz, S. Alvarez and M. Verdaguer, "Spin density distribution in transition metal complexes: Some thoughts and hints", Comments Inorg. Chem. 1998, 20, 27-56. |
F. Arnau, F. Mota, J. J. Novoa and S. Alvarez, "On the Existence of a Quadruplet Ground-State for the BO2 and AiO2 Molecules", Quantum Chemistry: Basic Aspects, Actual Trends 1989, 62, 377-383. |
M. Pérez-Jiménez, N. Curado, C. Maya, J. Campos, J. Jover, S. Alvarez, E. Carmona. "Coordination of LiH Molecules to Mo≣Mo Bonds. Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4and Mo6Li9H18Clusters”. J. Am. Chem. Soc., 2021, 143, 5222-5230. |
M. Pérez-Jiménez, N. Curado, C. Maya, J. Campos, E. Ruiz, S. Alvarez, E Carmona. “Experimental and Computational Studies on Quadruply Bonded Dimolybdenum Complexes with Terminal and Bridging Hydride Ligands”. Chem. Eur. J., 2021, 27, 6569-6578. |
A. Falceto and S. Alvarez. "Comparison of the Cr-Cr quadruple and quintuple bonding mechanisms". The Chemical Bond II, 100 Years Old and Getting Stronger: Struct. Bond., 2016, 170, 249-264. Doi: 10.1007/430_2015_191. |
A. Falceto, K. H. Theopold and S. Alvarez, "Cr-Cr Quintuple Bonding: Ligand Topology and Interplay Between Metal-Metal and Metal-Ligand Bonding". Inorg. Chem., 2015, 54, 10966-10977. Doi: 10.1021/acs.inorgchem.5b02059, open access.
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M. Carrasco, I. Mendoza, E. Alvarez, C. Maya, R. Peloso, A. Rodríguez, A. Falceto, S. Alvarez and E. Carmona. "Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands". Chem. Eur. J., 2015, 21, 410-421. Doi: 10.1002/chem.201404057 |
M. Carrasco, N. Curado, E. Álvarez, C. Maya, R. Peloso, M. L. Poveda, A. Rodriguez, E. Ruiz, S. Alvarez, E. Carmona, "Experimental and Theoretical Studies on Arene-Bridged Metal-Metal-Bonded Dimolybdenum Complexes", Chem. Eur. J. 2014, 20, 6092-6102. |
M. Carrasco, N. Curado, C. Maya, R. Peloso, A. Rodríguez, E. Ruiz, S. Alvarez, E. Carmona. "Interconversion of Quadruply- and Quintuply-Bonded Dimolybdenum Complexes by Reductive Elimination and Oxidative Addition Reactions of Dihydrogen", Angew. Chem. Int. Ed. 2013, 52, 3227. |
G. Aullon and S. Alvarez, "Pyramidality effect on metal-metal single bonds", J. Chem. Soc. Dalton Trans. 1997, 2681-2687. |
X. Y. Liu and S. Alvarez, "M2L6 complexes with triple Mo-Mo and W-W bonds: Molecular topology and inverted pyramidality effect", Inorg. Chem. 1997, 36, 1055-1060. |
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